CHEM3702 Inorganic and Organometallic Chemistry

2019

4.5

3 x 50-minute lectures weekly
3 x 6-hour laboratories per semester
3 x 6-hour project works per semester

1 CHEM1102 - Modern Chemistry
2 ^ CHEM2702 - Organic Reactions
Must Satisfy: (1 and 2)

CHEM8702 has been successfully completed

The aim is to provide students with an overview of the role and importance that transition metal ions play in inorganic chemistry and in organometallic chemistry. Secondly, students will learn to use the modern approach of molecular orbital theory to develop chemical bonding concepts across the periodic table, and so to acquire an understanding of ligand field theory. The spectral and magnetic properties of transition metal ions can then be understood at a sophisticated level, which allows these transition metals to be used diagnostically to identify and characterise compounds. Finally, this topic will present students with the fundamentals of inorganic chemical synthesis through a series of practical experiments. These practical experiments and the associated capstone activities will solidify students knowledge and skills in the inorganic chemistry field.

At the completion of the topic, students are expected to be able to:

1. Demonstrate an understanding about what various types transition metal compounds are and how the can be used
2. Understand the molecular orbital description for bonding in an octahedral coordination complex
3. Know about the synthesis, characterisation and reactivity of metal carbonyls and pie-complexes, including metal cyclopentadienyls
4. Understand the chemical bonding in metal carbonyl and metal pie-complexes
5. Be familiar with the major industrial catalytic processes that employ organometallic catalysts
6. Demonstrate an understanding of what metal clusters are, how they form and react and how their bonding can be understood
7. Be familiar with the method of uptake and retention of metal ions in biological systems
8. Use the concept of metal ion hydrolysis to understand and make limited predictions of metal ion speciation in aqueous solution
9. Handle and report on transition metal compounds, including those which are sensitive to air and/or moisture, competently in a laboratory with due regard to occupational health and safety
10. Evaluate and present results from laboratory work in written and verbal form